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This can either be due to the fact that the substance's properties do not meet any of the criteria in PRIO, which is good, or that the substance is not included in the references to which PRIO refers.
To get more information about hazard properties to assess whether your substance meets the criteria in PRIO, you can search in ECHA's Classification and Labelling Inventory. Beside a list of harmonised classifications, the C&L Inventory contains classification and labelling information notified by manufacturers and importers of substances Use the companies' self-classifications to assess whether the substance is a phase-out substance or a priority risk reduction substance. You can also request more information from your supplier regarding health and environmental properties or search the scientific literature yourself.